Research Profile

Reactive transition-metal oxides, -sulfides and -carbenes

  1. Aktivierung von C–H- und C–C-Bindungen durch „nackte” Übergangsmetalloxid-Kationen in der Gasphase

    C–H and C–C Bond Activation by Bare Transition-Metal Oxide Cations in the Gas Phase

    D. Schröder, H. Schwarz

    Angew. Chem., 107, 2126 - 2150 (1995), DOI: 10.1002/ange.19951071805;

    Angew. Chem. Int. Ed. Engl., 34, 1973 - 1995 (1995), DOI: 10.1002/anie.199519731

  2. Zur Koordination von molekularem Sauerstoff in drei repräsentativen Übergangsmetallkationen: FeO2+, CrO2+ und [CH3Re(O2)2O]+

    Coordination of Dioxygen in Three Representative Transition Metal Cations: FeO2+, CrO2+, and [CH3Re(O2)2O]+

    D. Schröder, A. Fiedler, W. A. Herrmann, H. Schwarz

    Angew. Chem., 107, 2714 - 2716 (1995), DOI: 10.1002/ange.19951072214;

    Angew. Chem. Int. Ed. Engl., 34, 2517 - 2520 (1995), DOI: 10.1002/anie.199525171

  3. Kupplung von Kohlendioxid und Methan durch einen Tantalkomplex in der Gasphase

    Tantalum-Mediated Coupling of Methane and Carbon Dioxide in the Gas Phase

    R. Wesendrup, H. Schwarz

    Angew. Chem., 107, 2176 - 2179 (1995), DOI: 10.1002/ange.19951071817;

    Angew. Chem. Int. Ed. Engl., 34, 2033 - 2035 (1995), DOI: 10.1002/anie.199520331

  4. Redox Properties of the Diatomic Bare Iron Chalcogenides FeO and FeS in the Gas Phase

    J. N. Harvey, C. Heinemann, A. Fiedler, D. Schröder, H. Schwarz

    Chem. Eur. J., 2, 1230 - 1234 (1996), DOI: 10.1002/chem.19960021008

  5. Chromium Dioxide Cation OCrO+ in the Gas Phase: Structure, Electronic States, and the Reactivity with Hydrogen and Hydrocarbons

    A. Fiedler, I. Kretzschmar, D. Schröder, H. Schwarz

    J. Am. Chem. Soc., 118, 9941 - 9952 (1996), DOI: 10.1021/ja960157k

  6. Relativistic effects in the cationic platinum carbene PtCH2+

    C. Heinemann, H. Schwarz, W. Koch, K. G. Dyall

    J. Chem. Phys., 104, 4642 - 4651 (1996), DOI: 10.1063/1.471210

  7. Effects of Sequential Ligation of Molybdenum Cation by Chalcogenides on Electronic Structure and Gas-Phase Reactivity

    I. Kretzschmar, A. Fiedler, J. N. Harvey, D. Schröder, H. Schwarz

    J. Phys. Chem. A, 101, 6252 - 6264 (1997), DOI: 10.1021/jp971941+