Research Profile

Mass-spectrometric approaches to stereoselectivity

  1. Diastereoselective Gas-Phase Carbon-Carbon Bond Activation Mediated by "Bare" Co+ Cations

    G. Hornung, D. Schröder, H. Schwarz

    J. Am. Chem. Soc., 117, 8192 - 8196 (1995), DOI: 10.1021/ja00136a017

  2. Synergy of Theory and Experiment in the Remote Functionalization of Aliphatic Nitriles by "Bare" Fe(I) and Co(I) Cations in the Gas Phase

    M. C. Holthausen, G. Hornung, D. Schröder, S. Sen, W. Koch, H. Schwarz

    Organometallics, 16, 3135 - 3147 (1997), DOI: 10.1021/om970229w

  3. Regiospecific and Diastereoselective C–H and C–Si Bond Activation of ω-Silyl-Substituted Alkane Nitriles by "Bare" Co+ Cations in the Gas Phase

    G. Hornung, D. Schröder, H. Schwarz

    J. Am. Chem. Soc., 119, 2273 - 2279 (1997), DOI: 10.1021/ja963254m

  4. The Origin of the Remarkable Regioselectivity of Fe+-Mediated Dehydrogenation in Benzocycloalkenes

    R. H. Hertwig, K. Seemeyer, H. Schwarz, W. Koch

    Chem. Eur. J., 3, 1315 - 1323 (1997), DOI: 10.1002/chem.19970030819