1. Direkte Umwandlung von Methan zu protoniertem Formaldehyd bei Raumtemperatur in der Gasphase: Zur Rolle von Quecksilber unter den Oxidkationen der Zinktriade

    Direct Room-Temperature Conversion of Methane into Protonated Formaldehyde: The Gas-Phase Chemistry of Mercury among the Zinc Triad Oxide Cations

    L. Yue, S. Zhou, X. Sun, M. Schlangen, H. Schwarz

    Angew. Chem., 130, 3306 - 3310 (2018), DOI: 10.1002/ange.201712405;

    Angew. Chem. Int. Ed., 57, 3251 - 3255 (2018), DOI: 10.1002/anie.201712405

  2. Über die Ursachen der deutlich unterschiedlichen Reaktivität von Ruthenium unter den [MO]+/CH4‐Systemen (M = Fe, Ru, Os)

    On the Origin of the Distinctly Different Reactivity Behavior of Ruthenium in [MO]+/CH4 Systems (M = Fe, Ru, Os)

    X. Sun, S. Zhou, L. Yue, M. Schlangen, H. Schwarz

    Angew. Chem., 130, 6039 - 6043 (2018), DOI: 10.1002/ange.201800173;

    Angew. Chem. Int. Ed., 57, 5934 - 5937 (2018), DOI: 10.1002/anie.201800173

  3. Ligand Effects on the Reactivity of [CoX]+ (X  =  CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+

    M. Firouzbakht, N. J. Rijs, M. Schlangen, M. Kaupp, H. Schwarz

    Top. Catal., 61, 575 - 584 (2018), DOI: 10.1007/s11244-018-0903-8

  4. Experimentelle Bestimmung des aktiven Zentrums im heteronuklearen Redox‐System [AlVOx]+•/CO/N2O (x = 3, 4) durch Gasphasen‐Infrarotspektroskopie

    Experimental Identification of the Active Site in the Heteronuclear [AlVOx]+•/CO/N2O (x = 3, 4) Redox Couples by Gas‐Phase IR Spectroscopy

    S. Debnath, H. Knorke, W. Schöllkopf, S. Zhou, K. R. Asmis, H. Schwarz

    Angew. Chem., 130, 7570 - 7574 (2018), DOI: 10.1002/ange.201804056;

    Angew. Chem. Int. Ed., 57, 7448 - 7452 (2018), DOI: 10.1002/anie.201804056

  5. Thermal O–H Bond Activation of Water as Mediated by Heteronuclear [Al2Mg2O5]•+: Evidence for Oxygen-Atom Scrambling

    C. Geng, J. Li, T. Weiske, H. Schwarz

    J. Am. Chem. Soc., 140, 9275 - 9281 (2018), DOI: 10.1021/jacs.8b05618

  6. Selective C‐O Coupling Hidden in the Thermal Reaction of [Al2CuO5]+ with Methane

    S. Zhou, X. Sun, L. Yue, M. Schlangen, H. Schwarz

    Chem. Eur. J., 24, 14649 - 14653 (2018), DOI: 10.1002/chem.201804059

  7. Elektrisches Feld als “smarter” Ligandenersatz zur kontrollierten thermischen Aktivierung von Methan und molekularem Wasserstoff

    The Electric Field as a "Smart" Ligand in Controlling the Thermal Activation of Methane and Molecular Hydrogen

    L. Yue, N. Wang, S. Zhou, X. Sun, M. Schlangen, H. Schwarz

    Angew. Chem., 130, Early View (2018), DOI: 10.1002/ange.201805718;

    Angew. Chem. Int. Ed., 57, Early View (2018), DOI: 10.1002/anie.201805718

  8. Oriented External Electric Fields as a Mimic for Probing the Role of Metal Ions and Ligands in the Thermal Gas-Phase Activation of Methane

    C. Geng, J. Li, M. Schlangen, S. Shaik, X. Sun, N. Wang, T. Weiske, L. Yue, S. Zhou, H. Schwarz

    Dalton Trans., 47, Early View (2018), DOI: 10.1039/C8DT03048K

  9. Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON]+/CH4 System

    Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON]+/CH4 System

    S. Zhou, X. Sun, L. Yue, C. Guo, M. Schlangen, H. Schwarz

    Angew. Chem., 130, Accepted Article (2018), DOI: 10.1002/ange.201809583;

    Angew. Chem. Int. Ed., 57, Accepted Article (2018), DOI: 10.1002/anie.201809583