1. Direkte Umwandlung von Methan zu protoniertem Formaldehyd bei Raumtemperatur in der Gasphase: Zur Rolle von Quecksilber unter den Oxidkationen der Zinktriade

    Direct Room-Temperature Conversion of Methane into Protonated Formaldehyde: The Gas-Phase Chemistry of Mercury among the Zinc Triad Oxide Cations

    L. YueORCID iD icon, S. ZhouORCID iD icon, X. Sun, M. SchlangenORCID iD icon, H. SchwarzORCID iD icon

    Angew. Chem., 130, 3306 - 3310 (2018), DOI: 10.1002/ange.201712405;

    Angew. Chem. Int. Ed., 57, 3251 - 3255 (2018), DOI: 10.1002/anie.201712405

  2. Über die Ursachen der deutlich unterschiedlichen Reaktivität von Ruthenium unter den [MO]+/CH4‐Systemen (M = Fe, Ru, Os)

    On the Origin of the Distinctly Different Reactivity Behavior of Ruthenium in [MO]+/CH4 Systems (M = Fe, Ru, Os)

    X. Sun, S. ZhouORCID iD icon, L. YueORCID iD icon, M. SchlangenORCID iD icon, H. SchwarzORCID iD icon

    Angew. Chem., 130, 6039 - 6043 (2018), DOI: 10.1002/ange.201800173;

    Angew. Chem. Int. Ed., 57, 5934 - 5937 (2018), DOI: 10.1002/anie.201800173

  3. Ligand Effects on the Reactivity of [CoX]+ (X  =  CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+

    M. FirouzbakhtORCID iD icon, N. J. RijsORCID iD icon, M. SchlangenORCID iD icon, M. KauppORCID iD icon, H. SchwarzORCID iD icon

    Top. Catal., 61, 575 - 584 (2018), DOI: 10.1007/s11244-018-0903-8

  4. Experimentelle Bestimmung des aktiven Zentrums im heteronuklearen Redox‐System [AlVOx]+•/CO/N2O (x = 3, 4) durch Gasphasen‐Infrarotspektroskopie

    Experimental Identification of the Active Site in the Heteronuclear [AlVOx]+•/CO/N2O (x = 3, 4) Redox Couples by Gas‐Phase IR Spectroscopy

    S. DebnathORCID iD icon, H. KnorkeORCID iD icon, W. SchöllkopfORCID iD icon, S. ZhouORCID iD icon, K. R. AsmisORCID iD icon, H. SchwarzORCID iD icon

    Angew. Chem., 130, 7570 - 7574 (2018), DOI: 10.1002/ange.201804056;

    Angew. Chem. Int. Ed., 57, 7448 - 7452 (2018), DOI: 10.1002/anie.201804056

  5. Thermal O–H Bond Activation of Water as Mediated by Heteronuclear [Al2Mg2O5]•+: Evidence for Oxygen-Atom Scrambling

    C. GengORCID iD icon, J. LiORCID iD icon, T. WeiskeORCID iD icon, H. SchwarzORCID iD icon

    J. Am. Chem. Soc., 140, 9275 - 9281 (2018), DOI: 10.1021/jacs.8b05618

  6. Selective C‐O Coupling Hidden in the Thermal Reaction of [Al2CuO5]+ with Methane

    S. ZhouORCID iD icon, X. Sun, L. YueORCID iD icon, M. SchlangenORCID iD icon, H. SchwarzORCID iD icon

    Chem. Eur. J., 24, 14649 - 14653 (2018), DOI: 10.1002/chem.201804059

  7. Elektrisches Feld als “smarter” Ligandenersatz zur kontrollierten thermischen Aktivierung von Methan und molekularem Wasserstoff

    The Electric Field as a "Smart" Ligand in Controlling the Thermal Activation of Methane and Molecular Hydrogen

    L. YueORCID iD icon, N. Wang, S. ZhouORCID iD icon, X. Sun, M. SchlangenORCID iD icon, H. SchwarzORCID iD icon

    Angew. Chem., 130, 14845 - 14849 (2018), DOI: 10.1002/ange.201805718;

    Angew. Chem. Int. Ed., 57, 14635 - 14639 (2018), DOI: 10.1002/anie.201805718

  8. Oriented External Electric Fields as a Mimic for Probing the Role of Metal Ions and Ligands in the Thermal Gas-Phase Activation of Methane

    C. GengORCID iD icon, J. LiORCID iD icon, M. SchlangenORCID iD icon, S. ShaikORCID iD icon, X. Sun, N. Wang, T. WeiskeORCID iD icon, L. YueORCID iD icon, S. ZhouORCID iD icon, H. SchwarzORCID iD icon

    Dalton Trans., 47, 15271 - 15277 (2018), DOI: 10.1039/C8DT03048K

  9. Ta2+-mediated ammonia synthesis from N2 and H2 at ambient temperature

    C. GengORCID iD icon, J. LiORCID iD icon, T. WeiskeORCID iD icon, H. SchwarzORCID iD icon

    Proc. Natl. Acad. Sci. U.S.A., 115, 11680 - 11687 (2018), DOI: 10.1073/pnas.1814610115

  10. Selektive Übertragung eines Stickstoffatoms im [CeON]+/CH4 System durch hocheffizientes Intersystem Crossing

    Selective Nitrogen-Atom Transfer Driven by a Highly Efficient Intersystem Crossing in the [CeON]+/CH4 System

    S. ZhouORCID iD icon, X. Sun, L. YueORCID iD icon, C. Guo, M. SchlangenORCID iD icon, H. SchwarzORCID iD icon

    Angew. Chem., 130, 16129 - 16133 (2018), DOI: 10.1002/ange.201809583;

    Angew. Chem. Int. Ed., 57, 15902 - 15906 (2018), DOI: 10.1002/anie.201809583